Charles E. Taylor, Jonathan T. Kwan's Advances in the Studies of Gas Hydrates PDF

By Charles E. Taylor, Jonathan T. Kwan

ISBN-10: 1441934510

ISBN-13: 9781441934512

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B. Physica D, 1993,69, 189. 19. Cahn, J. ; Hilliard, J. E. J. Chem. Phys, 1958, 28, 258; 1959, 31, 688. 20. Kelton, K. F. , 1991,45, 75. 21. Kelton, K. ; Greer, A. L. Phys. Rev. B, 1988, 38, 10089. 22. ; Warren, J. ; Douglas, J. ; Ferreiro, V. , 2003, 2, 92. 23. ,Warren, J. ; Carter, W. C. Physica D, 1998, 119, 415. 24. Warren, J. ; Douglas, J. F. Proc. TMS Ann. Meeting, San Francisco, 2004, accepted for publication. 25. ; Tanaka, H. J. Phys. , 1995, 99, 7114. 26. Kvamme, B. unpublished. 27. Stewart, P.

I. Chem. Eng. , 2003, 58, 27. 11. van Hinsberg, M. G. E. PhD Thesis; Univ. of Amsterdam, 1994. 12. Pomeransky, A. ; Belosludov, V. ; and Inerbaev, T. M. This book, p. 130. This page intentionally left blank 3 Phenomenological Modeling of Hydrate Formation and Dissociation Maria Carolina Gonzalez Chacin, Richard G. Hughes,* Faruk Civan, and Charles E. Taylor 1. INTRODUCTION Since the pioneering work of Hammerschmidt [1], the hydrate formation and dissociation phenomena have been the subject of numerous studies (Sloan, [2], and Makogan, [4]).

The water vapor pressure can be neglected and the gas phase is assumed pure methane. Further, can be estimated using an equation of state for the liquid system, but the mole fraction of the gas in the liquid cannot be determined at non-equilibrium conditions. The concentration of the gas in the liquid will vary with the distance from the interface and this variation will be related to the mixing rate, among other factors. Therefore, there are many factors that can interfere with the calculation adding errors to the expression of the driving force and the reaction rate.

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Advances in the Studies of Gas Hydrates by Charles E. Taylor, Jonathan T. Kwan

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